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Environmental protection has been in focus for many years and especially clean water is scarce in many places. Water treatment issues are becoming increasingly important for the pulp and paper Industry as extensive amounts of water are used in the production processes.

 

Biological treatment has for some time been state of the art for effluent treatment but as energy costs are soaring new ways of minimizing treatment costs are sought. Increased water reuse by closing up water circuits without ruining the quality of final products is an important aspect. Pretreatment of selected process streams prior to external treatment will in many cases be beneficial from both cost and environmental points of view.

 

The focus on the environmental impacts of pulp and paper mill effluent have in recent years shifted from broad terms such as color, suspended solids and organic matter to more specific terms like sterols and “endocrine disruptors”. The interest for specialized effluent treatment methods is growing as mills will have to monitor their emissions in much more detail in the future.

 

Several methods of removing different types of organic matter are described. The removal efficiency differs considerably between various treatment procedures. Low molecular mass material is easily degraded by biological means whereas more complex, often colored, compounds like lignin and lignans call for more advanced treatment methods.

Waste water treatment for pulp & paper

Since the early eighties, anaerobic wastewater treatment is successfully applied in pulp & paper industry. The first applications of anaerobic technology in pulp & paper industry were in recycle paper factories as they produce excessive wastewater from the production processes. Later also pulp mill related effluents (such as BCTMP, NSSC and chemical pulp condensates) were successfully treated in anaerobic reactors. The organic compounds present in pulp & paper wastewater can easily be converted into biogas. Biogas can be used as a renewable energy source, to reduce the fossil fuel and/or electricity demand of the mill.

If combined anaerobic and aerobic treatment is applied, very strict effluent limits can be reached. Effluent of the wastewater treatment plant could even be re-used in the mill. In comparison to full aerobic treatment, combined anaerobic - aerobic treatment reduces the energy needs and operations costs of the wastewater treatment plant considerably. Also the required surface area and the sludge production are significantly lower.

The wastewaters generated from production processes of this industry include high concentration of chemicals such as sodium hydroxide, sodium carbonate, sodium sulfide, bisulfites, elemental chlorine or chlorine dioxide, calcium oxide, hydrochloric acid, etc (Sumathi & Hung, 2006). The major problems of the wastewaters are high organic content (20-110 kg COD/air dried ton paper), dark brown coloration, adsorbable organic halide (AOX), toxic pollutants, etc.

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